PokéBase - Pokémon Q&A
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I play LeafGreen, and on Two Island there is this lady who lives out on the cape and she says she has perfected the ultimate fighting move but has no one to teach it to. I've tried having every different Pokemon with me and she won't teach the move! So what's up with that? Is there a certain Pokemon I need, or is Game Freak trolling me?

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A woman at Two Island's Cape Brink will teach one move to each of the fully evolved Kanto starter Pokémon. She will teach Frenzy Plant to Venusaur, Hydro Cannon to Blastoise, and Blast Burn to Charizard. The moves can only be taught to one of these three Pokémon once, and the Pokémon learning the move must have maximum friendship.

https://m.bulbapedia.bulbagarden.net/wiki/Move_Tutor

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Thanks a ton!