In a Rotation Battle, Ally Switch has no effect.
According to Bulbapedia:
Ally Switch causes the user to switch places with the ally opposite to itself, and is an increased-priority move. It will fail if the user is in the middle of the field in a Triple Battle, if the user has no ally opposite it, or if used in a Single Battle, Multi Battle, Rotation Battle, or Horde Encounter.
Source
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