PokéBase - Pokémon Q&A
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3 Answers

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No the only way to get him is to trade or migrate him from previous games look on pokedex pages for where you can catch pokemon.

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Note that NONE of the starter Pokemon of any generation are able to be caught.
yea but i was talking about any other pokemon and the pages do tell you where you can get them even though its the city you start in
so no more questions like this come up
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No you cannot catch it in game but you can use poke transfer and transfer it to your new game.this only works if you have an older game such as heartgold

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No. You can't catch a Charmander in the Unova Region, UNLESS, you use an action replay to hack and catch it,AND you can also use poke transfer to migrate a Charmander from previous generations such as diamond,pearl,platinum,leafgreen,firered,ruby,sapphire,emerald,red, and blue. (HOPE THIS HELPS!!!) :)

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What is action replay?
A hacking device.