PokéBase - Pokémon Q&A
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They are held by wild Trubbish and wild Garbodor.
5% chance for Trubbish.
50% for Garbodor.

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In Black and White, there is a 5% chance that a Trubbish, Croagunk, or Toxicroak will be holding Black Sludge and a 50% chance that Garbodor will be holding it.

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True, they are held by Trubbish and Garbodor, but the percentage is incorrect. It is a 50% chance. My source is Bulbapedia.

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I just looked at Garbodor, it said 50%
For Trubbish, I mean.
That explains the 1% Nugget