Meta Battle Subway PokeBase - Pokemon Q&A
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Routes 19, 20, 21, 34, 40, 41 + Cherrygrove City, Cianwood City, and Olivine City contain Staryu. Hope I helped :)

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At night,right?
Please use the comment system and yes there are charts on the pages that the links lead to that show you when, how, and what percent they are found.