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No ubers allowed. I want one that gives pure sp defense, not defense and sp defense like shuckle or vespiquen.

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These Pokemon are over level 40 and gives Sp Defense EVs:
Altaria gives 2 Sp Defense EVs.
Seel gives out 1 Sp Defense EV.
Dewgong gives out 2 Sp Defense EVs.
Ledian gives out 2 Sp Defense EVs.
Politoed gives out 3 Sp Defense EVs.
Slowking gives out 3 Sp Defense EVs. (It is at level 35-70)
Misdreavus gives out 1 Sp Defense EV. (It is only in White. It is only above level 40 in thick grass)
Mantine gives out 2 Sp Defense EVs. (It is level 35-70)
Claydol gives out 2 Sp Defense EVs.
Milotic gives out 2 Sp Defense EVs.
Mantyke gives out 1 Sp Defense EV. (It's at level 25-55)

In Short
Altaria
Seel
Dewgong
Ledian
Politoed
Slowking
Misdreavus
Mantine
Claydol
Milotic
Mantyke

Source
Full List

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thanks!
no prob. :)