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No ubers allowed. I would apreciat epokemon above lv 40.

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The only Pokemon in White that gives off those EVs is Scrafty, which cannot be found in the wild.
Other Pokemon: Probopass, Dusknoir, Uxie, Wormadam-Trash, Spiritomb, Bronzong, Vespiquen, Registeel, Dusclops, Corsola, Shuckle, Suicune, Bayleef, Meganium, Wartortle.

This is assuming you haven't beat the Elite Four.

If you have: Bronzong, Vespiquen, Corsola, and Shuckle would be the ones.

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thanks!
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The following Pokemon give both:
Wartortle
Bayleef
Meganium
Vespiquen
Spiritomb
Uxie
Dusclops
Dusknoir
Shuckle
Wormadam (trash cloak)
Bronzong
Scrafty

So in short. Only Scrafty will give of both. He gives one EV in each stat.

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Yes, there is. Scrafty does. He/she gives 1 Special Defense EV, and 1 Defense EV.
You can't Scrafty in the wild, though.
Shuckle also gives out 1 Special Defence EV, and 1 Defense EV.
Shuckle can be found on Route 14, after you beat the Elite-Four.
Vespiqueen gives them out also.
Vespiqueen can be found on Route 12, after you beat the Elite-Four.
Corsola does, too.
Corsola can be found on Route 13, Undella Town, after you beat the Elite-Four.
So does Bronzong.
It can be found at Abundant Shrine, after you beat the Elite-Four.

So in short, the Pokemon that are in B/W are:
Scrafty
Shuckle
Vespiqueen
Corsola

Bronzong

Others include: Probopass, Dusknoir, Uxie, Wormadam-Trash, Spiritomb, Registeel, Dusclops, Suicune, Bayleef, Meganium, Wartortle.

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