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In the anime, does Ash have a shiny Noctowl? If so, how did he catch it?

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Yeah, he does :D.

This Pokémon was seen in early Johto. It was being researched by a
Pokémon Researcher. he tried to catch it but failed. Ash however
managed to successfully battle it with Pikachu and caught it. It
became a very important member of Ash's team and helped him win many
Gym Battles & League Matches in the Johto League. It currently spends
it's time at Oak's Lab in Pallet Town

First Seen: Episode 156: Fowl Play

http://www.serebii.net/anime/shiny/noctowl.shtml

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