PokéBase - Pokémon Q&A
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I want him to know:
Ice fang
Fire fang
Thunder fang (He already knows it)
Crunch (He already knows it)

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Breed a female Shinx, Luxio, or Luxray with a male Arbok, Snubull, Granbull, Hippowdon, Stoutland, or Exploud that knows Thunder Fang, Ice Fang, and Fire Fang. The baby Shinx should know them. Level Shinx up and evolve it into a Luxray. Reach Level 42 for Crunch. Or you can rbeed a female Shinx, Luxio, or Luxray with a male Arbok, Snubull, Granbull, Hippowdon, Stoutland, or Exploud that knows Crunch, Thunder Fang, Ice Fang, and Fire Fang. The baby Shinx should know all of them. Evolve it into Luxray, and you're done!

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but they learn them at lv1 how can I get them at lv1? I have a real question about it.
you've posted two same questions: One hippowdon and the other luxray. why not ask one as the answer would be the same?
that will take forever but OK.