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My Ralts has Synchronise and I'm wondering, if I give her a toxic orb and poison it, will it poison my foe?

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>Synchronize passes on status problems to the opponent that caused the problem. Synchronize will not pass on the Sleep or Frozen status conditions, or if the status condition was obtained from items such as the Flame Orb.

No it wont the opponent has to be the one to cause the status effect.

Source-Experience and This

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Thanks :)