Ok, I am just doing the main protaganists for this, although all the instances are very rare anyway, let's keep this simple.
- 30x Tauros using Safari Balls
- Totodile with a Lure Ball
- I don't think it mentions it in my source, but I'm pretty sure Ash's Beedrill was caught in a Park Ball as well (although he gave Beedrill away later that episode anyway)
- Pineco using a Fast Ball
- Corsola using a Lure Ball