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Is it learned by egg moves or something else?

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Froakie can't learn Spikes actually, it's Greninja that can. It learns it at level 28, but since this is impossible as the lowest level Greninja can be at is 36, you'll have to go to the Move Relearner, give him a Heart Scale and teach it to it there.

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Ah, I see. Thanks once again! :)
No problem ;)