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I'm using my meowstic to take heart scales but the luvdiscs I find don't really have them anymore...

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A tip get Thief TM46 and give it to a Pokemon or use Covet that Dragoon Suggested (Eevee learns it!). Then you fish with a old rod and you mustn't catch it.

Source Serebii and Doing it

TM 87 ~(★-♡)~

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I actually just used covet :P
I can add that too
I give thief to a Noivern with Frisk, because then I know for sure whether the wild pokemon has an item. Other pokemon with Frisk no doubt can learn Thief as well, but Noivern just happens to be the one I use.
I taught my zoroark thief, and without Frisk, I got a heart scale from luvdisc