PokéBase - Pokémon Q&A
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I'm up for some trolling on 1v1

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Yes, there are more.

Two Pokemon can learn these moves:

  • Deoxys(all forms)
  • Smeargle

Source: /dexsearch command on Showdown

Edit: Grumpig can't, it is a mistake on PS. It can only learn Magic coat and Mirror coat.
Hope I helped.

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