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If a Gale Wings Talonflame uses Brave Bird and my Toxicroak uses Sucker Punch, which would go first?

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Talonflame would because in a priority tie the one with the higher speed stat goes first.
Also there's this:
> Moves with a higher priority always go first, regardless of a Pokémon's speed. If two moves with the same priority are used, the faster Pokémon goes first as usual.

Source: Experience + Knowledge and DB page on Sucker Punch

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D: 8 seconds
^ same source
1 thing to add is that if they got same speed it´s 50/50
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talonflame if both had max speed