PokéBase - Pokémon Q&A
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Just curious.
Been getting a lot of 'em lately.

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>During special distribution periods, players can receive special O-Powers by playing their games at a Pokémon Center store; O-Power S is exclusive to this method, although the O-Powers given out are not always S.

So you can only acquire it if you're playing in a Pokemon Center store (link for locations.)


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