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From gen 1-6, every shiny-locked Pokemon.

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Shiny Locks only began in the Gen V games.


Shiny Locked

Gen V
Zekrom, Reshiram, Victini

Gen VI
Articuno, Zapdos, Moltres, Mewtwo, Xerneas, Yveltal, Zygarde, Groudon, Kyogre, Rayquaza, Deoxys

Serebii


However, before the Gen V Games there were still unobtainable Shiny Pokemon, as a result of being directly distributed from events. These are not technically "Shiny Locked" but I'll list them below;

Gen II
Mew

Gen III
Celebi

Gen IV
Spiky-eared Pichu, Arceus, Celebi

Gen V
Celebi, Arceus, Keldeo, Meloetta

Generation VI
Cosplay Pikachu, Celebi, Arceus, Victini, Keldeo, Meloetta, Diancie

This also factors in that some Pokemon can only be received in a particular game by trading from a previous game, in which they may have not been available as a Shiny.

Bulbapedia

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