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So I've been playing showdown for maybe a week or so, and I want some of the Pokemon from there to get into ORAS.

My question is

Adamant or Jolly?

How do I get a technician ambipom by breeding aipom?

Item: life orb, silk scarf, or a different item?

EV spread? Is 252 spe 252 Atk and 4 def ok?

Moves:
Fake Out
Knock Off
Low Kick
Return?

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Best answer

Ambipom

Ambipom @ Life Orb
Ability: Technician
EVs: 252 Atk / 4 Def / 252 Spe
Jolly Nature
- Fake Out
- Return
- Low Kick
- Knock Off

And to answer your question, in Generation VI, any Pokémon, including male and genderless Pokémon, can pass down their Hidden Ability when bred with Ditto. Ditto's Ability is irrelevant to inheritance. If the male is bred with another Pokémon from the same egg group, Hidden Abilities will not be passed down.

To initially get a Hidden Ability Ambipom / Aipom, you have to receive it from a trade or visit a Friend Safari. You will then be able to breed the Hidden Ability Pokemon with Ditto who will pass it down.

Source: http://bulbapedia.bulbagarden.net/wiki/Pokémon_breeding

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But this is in ORAS? And technician is'nt ambipoms hidden ability. The moveset was also from smogon, and i wanted to know if there was any alternative to any of this. For example, does a pickup aipom evolve into technician ambipom or does run away aipom evolve into technician ambipom?
ORAS Game Location: Routes 118 and 121 (DexNav)

This moveset is probably the best and most used for Ambipom at the moment.

And to answer your question, the only thing you need to do is get a Aipom with the ability Run Away, not Pick-Up. When you evolve it, it will evolve into an Ambipom with Technician. If done otherwise, you will have an Ambipom with Pick-Up.