PokéBase - Pokémon Q&A
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You can't get a ambipom in heart or soul silver but you can get a aipom and evolve it. You can find a aipom at Routes 28, 33, 42, 44, 45, 46, Azalea Town, and Mt. Silver (Headbutt)

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more info on the evolve part. get aipom to learn double hit and level it up lv 32.