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Breeding competitive ambipom?

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So ive never bred for competitive use before, so is there any good guide on how to breed IV's EV's and abilities/natures for ambipom?(or any other Pokemon) and maybe a guide for using power items?

And how do you EV train without super training?

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Read the passing down IVs section on this page to help you with your breeding.

You could try EV training with hordes instead of super training

Hope I helped!

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How do you EV train specificic stats with hordes?
Refer to this extremely helpful page: http://www.smogon.com/forums/threads/a-guide-to-ev-training-with-hordes.3490052/
Infect the Pokémon you want to train with Pokérus (if any of your Pokémon have it), give it a Power item/Macho Brace, and refer to the aforementioned site for the route with the right EV-giving hordes.