There's no guaranteed way to get the 5IV male Ralts, but since you're breeding 5IV and 6IV parents, the only real problem will be getting a male with 5IVs.
1 – Give the Adamant female Ralts an Everstone to pass down her nature.
2 – Give the male Ralts a Destiny Knot. This passes down any 5IVs between the two parents and greatly increases your chance of getting a 5IV baby.
3 – Breed! Keep hatching those Eggs until you get the Ralts you want. There's no telling how long it could take; I got my 5IV male Marill on my 12th Egg, while another time it took me 45+ Eggs to breed a 5IV male Shellos. Just be patient, and you will eventually get the right Ralts.