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I remember this happening in the third generation games every once in a while, but after those games it's never happened. Has this ever occured in Black/White to you? And, if you know, what is the probability of this happening?

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Yes, People in the Cold Storage explain that if you are Lucky enough, you can get an extra Can or Bottle. The Probability is about 1 in 100. Hope this helps...

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Thank you(:
Yeah, what PokemonBlack10 said. I bought 6 soda pops and 6 lemanads and got a free one too. I don't think it works with fresh waters, though...
Nah it works with Fresh Water too. Did you know it's WAAAY cheaper to buy Fresh Waters instead of Super Potions? Of course yall did. :)