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I'm kind of curious. The only ones I know are Shedinja and Chatot.

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Just a heads up, this answer may take me a while to fully complete.

Nidoqueen
EVs: 3 HP
Highest stat: Attack

Venonat
EVs: 1 Sp. Def
Highest stat: HP

Slacking
EVs: 3 HP
Highest stat: Attack

Shedinja
EVs: 2 HP
Highest Stat: Attack

Barboach
EVs: 1 HP
Highest stat: Speed

Metagross
EVs: 3 Defense
Highest stat: Attack

Budew
EVs: 1 Sp. Atk
Highest stat: Sp. Def

Chatot
EVs: 1 Attack
Highest stat: Speed & Sp. Atk

Yanmega
EVs: 2 Attack
Highest stat: Sp. Atk

Heat, Wash, Frost, Fan, and Mow Rotom
EVs: 1 Sp. Atk & 1 Speed
Highest stats: Defense & Sp. Def

Shaymin Sky
EVs: 3 HP
Highest stat: Speed

Mandibuzz
EVs: 2 Sp. Atk
Highest stat: HP

Tornadus (Incarnate)
EVs: 3 Attack
Highest stat: Sp. Atk

Thundurus (Incarnate)
EVs: 3 Attack
Highest stat: Sp. Atk

Landorus (Incarnate)
EVs: 3 Sp. Atk
Highest stat: Attack

Digersby
EVs: 2 Attack
Highest stat: HP

Aegislash (Blade)
EVs: 2 Defense & 1 Sp. Def
Highest stat: Attack & Sp. Atk

Barbaracle
EVs: 2 Attack
Highest stat: Defense

Clauncher
EVs: 1 Sp. Atk
Highest stat: Sp. Def

Hawlucha
EVs: 2 Attack
Highest stat: Speed

Xenreas
EVs: 3 HP
Highest stats: Attack & Sp. Atk

Yveltal
EVs: 3 HP
Highest stats: Attack & Sp. Atk

Zygarde
EVs: 3 HP
Highest stat: Defense

Mega Diancie
EVs: 1 Defense & 2 Sp. Def
Highest stats: Attack & Sp. Atk

Mega Venusaur
EVs: 2 Sp. Atk & 1 Sp. Def
Highest stat: Defense

Mega Blastoise
EVs: 3 Sp. Def
Highest stat: Defense

Mega Kangaskhan
EVs: 2 HP
Highest stat: Attack

Mega Mewtwo X
EVs: 3 Sp. Atk
Highest stat: Attack

Mega Pidgeot
EVs: 3 Speed
Highest stat: Sp. Atk

Mega Altaria
EVs: 2 Sp. Def
Highest stats: Attack, Defense, & Sp. Atk

Mega Glalie
EVs: 2 HP
Highest stats: Attack & Sp. Attack

Mega Lopunny
EVs: 2 Speed
Highest stat: Attack

Mega Audino
EVs: 2 HP
Highest stats: Defens & Sp. Def

NOTE: This is going off of base stats, not minimum or maximum stats.

Hope this helps!

Sources:
I've got 721 of them.

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Thanks! though the alternate forms and megas were kind of obvious. I feel stupid for not thinking of them earlier.
No problem