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so without thunking I evolved roselia into roserade at level 5 and now at level 50 I realize it hasnt learned toxic spikes... wondering if theres a way to make it learn or if I messed up because the heart scale guy cant make it remember...

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No it can't, it can only learn it as a Roselia at level 28. If you want a move that can inflict poison you can always teach it toxic through tm.

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