PokéBase - Pokémon Q&A
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http://www.serebii.net/pokemon/xyzforms.shtml
In this link above, you can see Zygarde's new released forms. For Perfect Forme, it says that "when the Zygarde 50% Forme, the one obtainable in X & Y, cannot defeat an opponent in battle, it unleashes its power to become Zygarde's Perfect Forme". Could I stage exactly that to obtain it?

Proabbly not...

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No, you cannot as of yet.

Zygarde Perfect Forme, Zygarde 10% Forme, Zygarde Core and Zygarde Cell have not been coded into XY, the only games at the moment where you can obtain Zygarde. You'll have to be patient and wait for the 2016 release.

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The 2016 release of what?
Probably pokemon Z
TPCI hinted at a big release next year to commemorate tthe 20th anniversary of Pokémon. The new information reveals a bunch of Zygarde formes and that the next season of anime will be called XY&Z, basically confirming a Kalos remake / sequel / prequel.
Pokemon Z...Thanks!