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If I have a shedinja hold a focus sash and then use toxic, can I alternate protect and endure? Or would one of them fail?

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If you have a shedinja use toxic holding a focus sash, then as long as the opponent isn't steel/poison type and toxic doesn't miss, that part will work.

However, you cannot use any two types of protection moves together, including endure.

Source: Personal experience + tested it out on PS! to confirm.

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