PokéBase - Pokémon Q&A
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I need it so that my pokedex can be filled up and I can't find the trainer that uses it

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The Trainer that uses Mothim is Ace Trainer Ernest on Route 210.

If you need help finding Pokémon for your Dex in the future, this website has a list of all places to encounter Sinnoh Pokémon. This includes Trainer battles :)

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Thank you so much
No problem :3