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Is it like an event or something?

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There was an event in FRLG and Emerald, and that event Deoxys had a chance to be shiny.

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Nope, I believe it's only available via hack or soft resetting from the game you can catch it in (I believe it's Emerald) plus also from the Fire Red/Leaf Green and Emerald event which had a chance to be shiny (enabling you to soft reset for shininess).

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