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Is it after game?

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You get Volcarona (Level 35) after the 5th gym, in Relic Castle. To get there, you need to get through the Relic Passage which is next to PWT.

Source- https://bulbapedia.bulbagarden.net/wiki/Relic_Castle

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The Quake Badge is the 5th gym leader, but thanks
Also is it shiny huntable?
I don't see why not.
yes (filler)