PokéBase - Pokémon Q&A
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It is impossible to paralyze any electric-type Pokémon in Gen 6 or 7. You could use Soak to change its type and then paralyze it while it’s water-type. Keep in mind that there’s still a good chance that it’ll have Volt Absorb as its ability, so you’ll likely have to rely on Stun Spore instead of Thunder Wave to paralyze it (this also applies if you’re trying to paralyze a Jolteon in Gen 5 or lower). If you’re in Gen 6 or 7, the paralysis will remain even after its type changes back.

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