PokéBase - Pokémon Q&A
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I’ve been trying to test out Alolan Muk with Power of Alchemy ability in singles, but when my ally faints, it doesn’t copy the ability. Why is that?

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It only works in doubles. When the ally faints, your Muk will receive that ability.

Source: If it did work in singles, I would have used reciever passimian with superpower by now. Also experience.

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