Evolve it as soon as possible. After level 21, the only move that's good in Munna's learnset is Psychic, which is also a TM. So it would likely be best to evolve as soon as possible for the stat boost.
Alternatively, it could be evolved after level 35, which is when Munna learns Calm Mind. However, setup is very rarely needed in-game.
Hope I helped!
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