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So I think I’ll include Pokémon belonging to Kings, related in the game to kings.

The only few I can think of are Calyrex (it’s got king in its title), Zacian and Zamazenta and AZ Floette.

I think maybe Rayquaza counts since it is the King of the sky?

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Slowking and Politoed, because of Kings Rock and Aegislash, due to Kings Shield, come to mind. Based on the criteria you're listing though, this might be too subjective a question for this site; you'd probably get better answers on some type of discussion forum or site

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I included Queens too, hope you don't mind :P

Arceus - Literally god

Aegislash - "Generations of kings were attended by these Pokémon, which used their spectral power to manipulate and control people and Pokémon."

Calyrex - "Calyrex is known in legend as a king that ruled over Galar in ancient times. It has the power to cause hearts to mend and plants to spring forth."

Spectrier/Glastrier - Calyrex's steeds

Serperior - Based on French royalty, the Regal Pokemon

Zoroark - King N's ace

Politoed - "The curled hair on Politoed’s head is proof of its status as a king. It is said that the longer and more curled the hair, the more respect this Pokémon earns from its peers."

Vespiquen - Has "queen" in it's name and is the queen of the Combee colony

Eternal Flower Floette - AZ's Floette

Tyrantrum - "A single bite of Tyrantrum’s massive jaws will demolish a car. This Pokémon was the king of the ancient world."

Slowking - King of intelligence. "Slowking can solve any problem presented to it, but no one can understand a thing Slowking says."

Nidoking - King of battle. "Nidoking prides itself on its strength. It’s forceful and spirited in battle, making use of its thick tail and diamond-crushing horn."

Tsareena - It's signature ability is "Queenly Majesty" and a Tsar (Tsareena) is an emperor of Russia

Jynx - "In certain parts of Galar, Jynx was once feared and worshiped as the Queen of Ice."

Rayquaza - As you said, "King of the skies" (and king of competitive)

Groudon - King of the earth

Kyogre - King of the sea

Palkia - King of space

Dialga - King of time

Giratina - King of the Distortion World

Reshiram - Queen of fire and truth

Zekrom - King of electricity and ideals

Kyurem - King of ice and emptiness

Xerneas - King of life

Yveltal - King of death

Zygarde - King of balance and the ecosystem

The Tapus - Guardian deities

Solgaleo - King of the sun

Lunala - Queen of the moon

Zacian - "Able to cut down anything with a single strike, it became known as the Fairy King’s Sword, and it inspired awe in friend and foe alike."

Zamazenta - "Its ability to deflect any attack led to it being known as the Fighting Master’s Shield. It was feared and respected by all."

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Awesome.
U forgot nidoqueen
Nidoqueen isn't really a Queen of anything though.