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Does the ability Hustle activate when using a Max Move (i.e. when Dynamaxed)?

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Yes. Abilities don't lose effect when a Pokemon dynamaxes. Only items do.

Actually, there a few exceptions, like Gorilla Tactics and Sheer Force, that are disabled while Dynamaxed. Hustle, however, is not affected by Dynamax.

Hustle will work during Dynamax.

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So, Hustle will still increase physical damage dealt by 50%. However, will it affect the accuracy of Max Moves at all?
Hustle does not affect the accuracy of Max Moves.