PokéBase - Pokémon Q&A
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Sceptile is the basic options like mukuhawk say, but thats when its unboosted, with the clorophyl ability, a lot of pokes can outspeed sceptile with sunny day on, like Venusaur, Liligant, Maractus, Exegcutor, Victreebel, theres a lot more of clorophyl pokemon, but i only mentioned those who has a decent special attack stat

But my personal recomendations are Exegcutor, who has a great special attack stat, and Liligant, who has great speed and can learn quiver dance to keep boosting

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2 votes

/nds solar beam, sunny day, speed desc, grass:
Sceptile-Mega, Shaymin-Sky, Arceus-Grass, Sceptile, Whimsicott, Serperior, Jumpluff, Ogerpon, Ogerpon-Cornerstone, Ogerpon-Hearthflame

Sceptile-Mega is the fastest with 145 base spe, followed by Shaymin-Sky (127), Arceus-Grass (120), Sceptile (120) and so on.

Source: Pokemon Showdown! commands

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1 vote

Sceptile is the fastest grass type pokemon and can learn solarbeam and sunny day.
hope i helped :)

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prior to gen 5
oh since I know a lot that are faster.