PokéBase - Pokémon Q&A
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For the first time, Pokémon Mystery Dungeon Rescue Team DX includes Shiny Pokémon. These Pokémon will rarely appear in various dungeons as powerful bosses or in general and can require a lot of damage to be taken down. Normally they are just standard colours but you have a small chance of encountering them shiny. On the map, these Pokémon are marked with a yellow "Strong Foe" symbol

When taken down by your leader, there is a slim chance they will join you. However, if your leader has a Friend Bow equipped, there's a much greater chance they will join your team.

Only 27 Pokémon have the ability of being Shiny.

Source

Tl;Dr: Yes.

The list of Pokemon that can be shiny are

  • Butterfree
  • Ninetales
  • Rapidash
  • Electrode
  • Exeggcute
  • Exeggutor
  • Starmie
  • Magikarp
  • Gyarados
  • Ditto
  • Dragonite
  • Hoothoot
  • Noctowl
  • Ampharos
  • Azumarill
  • Sudowoodo
  • Aipom
  • Espeon
  • Wobbuffet
  • Shuckle
  • Corsola
  • Celebi
  • Spinda
  • Altaria
  • Zangoose
  • Metagross
  • Ambipom
  • Lickilicky

Hope this helps!

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