PokéBase - Pokémon Q&A
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You have a 4% chance of getting each one (25 natures total) or an 8% chance of getting one or the other. If you want a specific nature, then try using a pokemon with synchronize with the nature you want while catching pokemon. This will give a good chance for the wild pokemon to have the same nature. You can also breed a pokemon while the parent is holding an everstone and get the same result.

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Well that would be a problem, because i asked this for the sake of an Archen.....however, i did get a modest one.