PokéBase - Pokémon Q&A
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Timid Volcanions are very hindering, you should go with modest.

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It depends on what set you’re running. Generally I’d say to go with Timid to outspeed more, (I always prioritize speed over damage) but for a defensive set you’d probably want to go with Modest. I’ve even seen some Rash mixed attacker Volcanions that carry EQ.

I think one the most important things in Pokémon is experimenting. Switch between Timid and Modest, and see which one you’re inclined to.

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I was about to suggest the opposite xD

But your answer makes sense too.