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I am in the post game and want to know how to make the most money in the least amount of time. is challenging the E4 with an Amulet Coin the fastest way, or are there trainers that give you more money from rematches than a single E4 member?

I mainly ask because having to go through the Hall of Fame cutscene, save, softreset, reload the save, fly back to the E4, and spam through their dialogue takes longer than just running a bit to charge up my Vs. Seeker. So, if there are any trainers that give out close to what you get from Cynthia, rematching them would be faster imo

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There are two areas that have trainers you can rematch via VS Seeker and they both give more money then going through the E4 again and again and again.... (I too have suffered the same fate in other games)

the first area is near the Mansion on Route 212 there's an Old Couple there that gives you 48k each time you fight both of them with the Amulet Charm. Source https://www.serebii.net/pokearth/sinnoh/4th/route212.shtml

the second area is on Route 222 there's a Rich Boy Trey there who gives you 14k with Amulet Charm. https://www.serebii.net/pokearth/sinnoh/4th/route222.shtml

I use the Rich Boy as He's faster to beat but the Old Couple gives quiet a noticeable amount of extra money.

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I believe those trainers have different payouts before and after the Elite Four.
yeah but they all change the more you fight them with VS Seeker and these are post game answers for a post game question.