PokéBase - Pokémon Q&A
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You can find houndour on route 7 at night (Lv. 15) and also at the safari zone near Cianwood city Once you have completed 2 Challenges for Baoba (catch a geodude then catch a sandshrew) and you have the national dex. It will appear in the Savannah area once you have 4 forest Items placed. It will appear at level 41 or 42.

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Just to let you know Darquaza i'm not trying to be a smart alik but, you can only catch houndour in the safari zone in pokemon HeartGold. I just thought i'll let you know about that error...
Read this page:http://www.serebii.net/pokedex-dp/228.shtml
Houndour can be caught in HG/SS at route 7. It is very rare, even at night there is only 5% chance of catching it.
Ok DB-Valet, thanks for helpin' me out with that. My mistake...
np and welcome to the site :)