PokéBase - Pokémon Q&A
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Well OK so I used False Swipe and put to sleep, a level 2 Pidgey. Then I used the only Pokeball I had-A Premier Ball. So It didn't even shake once before the Pidgey got out! Are they meant for catching Pokemon?

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Premier balls have the same catch rate as a poke'ball. They just 'look cooler'.

http://www.serebii.net/itemdex/premierball.shtml

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lol 'look cooler'... thats what i thought