PokéBase - Pokémon Q&A
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cant believe blast burn hasnt been used

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>Baton Pass
Conversion(Banned Episode)
Blast Burn
Endeavor
Return
Role play
Block
Cosmic power
Follow Me
Grudge
SmellingSalt
Magnitude
Fissure

Okay I fixed some of the ones that were wrong earlier. This is a small list of the moves I decided to search. If you really want to know what hasnt been used go here and type up the move in the search. Click the go button and it will take you to the move's page.The page will tell you if it has been seen in the anime. There are so many to list though.

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Seriously hydro cannon? i saw barrys empoleon use hydro cannon
well like i said the list is outdated at the top
CURSE! no-one has used curse
im not putting all of them
i know but curse is a big one
u forgot me first that has never been in the anime