Pokémon Rate My Team
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AZ (Floette-Eternal) @ Life Orb
Ability: Sheer Force
EVs: 252 in all except Atk
Timid Nature
IVs: 0 Atk
- Moonblast
- Thunderbolt
- Wish
- Ice Beam

Yeet (Mewtwo-Mega-Y) @ Power Herb
Ability: Unburden
EVs: 252 in all except Atk
Modest Nature
IVs: 0 Atk
- Geomancy
- Stored Power
- Moongeist Beam
- Secret Sword

Noodle Arms (Deoxys-Speed) @ Focus Sash
Ability: Prankster
EVs: 252 HP in all except SpA
Jolly Nature
- Gastro Acid
- Stealth Rock
- Toxic Spikes
- Knock Off

Selene (Celesteela) @ Cell Battery
Ability: Flash Fire
EVs: 252 in all except SpA
Adamant Nature
- Heat Crash
- Sunsteel Strike
- Shore Up
- Spectral Thief

Snowy (Kyurem-White) @ Choice Specs
Ability: Refrigerate
EVs: 252 in all except Atk
Timid Nature
IVs: 0 Atk
- Boomburst
- Draco Meteor
- Earth Power
- Volt Switch

So based around this team, who should my sixth member be?

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I am pretty sure that Deoxys Speed, Floette-Eternal, and Celesteela aren't used in Balances Hackmons due to being relatively poor picks. I think replacing them would be more beneficial than giving your team a 6th member at this point. (sorry if this sounds a bit harsh). :P
maybe a, Arceus with a naughty nature and the moves Swords Dance, Psychic, Roost, your choice, and for the rest of the stuff you can choose.  :)

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I'm glad you asked! I have been setting up a team of my own, and is pretty much yours!
For me, I would add Mega Rayquaza.
Why?
This pokemon has one of the highest stats of any pokemon in existance and only challenged by few!
It's recommend to have Dragon Ascent to Mega Evolve, and other moves to counter ice and fairy types.
(Some of its few weaknesses) Have this pokemon with no special attacks so the two natures that boost
(-SpA/+Spd or -SpA/+A) will matter. Depending on if you are going against trainers or online players, natures matter. It will boost a statistic of a pokemon and reduce the stat that you aren't using, so win win!

I hope you choose this Pokemon to be on your team, and I hope I helped!

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I will consider adding Mega Rayquaza, thanks!
Most Mega Rayquaza sets in BH have Triage, Oblivion Wing, Giga Drain, Tail Glow, and some Dragon or Flying type special move so it isn't countered by Dazzling. :P
You do realize that Rayquaza can be already mega evolved regardless of its moves, right?
Glad I could help.

Also you can only mega evolve it using the move Dragon Ascent.
Choosing attack as your main stat to focus on (Attack and Special Attack are the same for Rayquaza and M Rayquaza) is extremely helpful.
Conclusion: This will improve its Dragon Ascent move and allow you to use those EVs for others.
No it doesn't need dragon ascent. I have a screenshot. https://imgur.com/a/viO2FxT