PokéBase - Pokémon Q&A
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As of Generation 8, these Pokemon can learn Volt Switch and U-Turn
Mew, Tapu Koko, Zapdos, Thundurus, Heliolisk, Togedemaru, Dedenne, Emolga, and Helioptile

Though it's not really worth running two pivot moves, as you're better off having one, and then just having another move slot for whatever you want

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These are the Pokemon that can learn both of these moves:
zapdos, mew, pachirisu, emolga, eelektrik, eelektross, and thundurus.

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Also Helioptile,Heliolisk and Dedenne after X and Y