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I'm trying to get free switch-outs on my Pokemon without resistance.

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Most Ground-types are immune to Volt Switch. But. For U-Turn, Fire-, Fighting-, Poison-, Flying-, Ghost-, Steel-, and Fairy-types would resist the move.
Seeing as damage isn't really the point of using U-Turn or Volt Switch in the first place, you shouldn't have to worry about Pokemon that resist the attacks. The only issue comes from Ground-types blocking Volt Switch, which is why U-Turn tends to be preferable even on Electric-types. Using both moves on the same set isn't advisable.

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Shedinja
Mega Charizard X
Nidoqueen & king
Alolan Diglett line
Magnemite line
Gligar line
Steelix (and mega)
Numel line
Mega Altaria
Primal Groudon
Regular and Heat Rotom
Dialga
Giratina
Excadrill
Galarian Yamask line
Galarian Stunfisk
Golett line
Reshiram
Landorus
Dragalge
Dedenne
Sandygast line
Turtonator
Togedemaru
Hakamo-o and Kommo-o
Tapu Koko
Naganadel
Toxel lone
Duraludon
Dreepy line
Eternatus

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