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I know that every Pokemon that the Elite Four and the Champion of Ruby, Sapphire, and Emerald knows either a damaging weather move (sandstorm/hail) or a fire, rock, ghost, or dark move. I remember some of the other Elite Four's Pokemon type, as well as some of the various Champion's Pokemon.

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ice elite 4's sealeo knows hail from my memory

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Here is a list of E4 Pokemon in Black White, Black White2, HG, SS, Platinum, and Diamond Pearl.

Black White:

Shantal: None

Grimsley: None

Caitlin: Musharna, Reuniclus, Metagross

Marshal: Breloom, Throh,

Alder: Vanilluxe

Black White 2:

Shantal: None

Grimsley: None

Caitlin: Musharna, Reuniclus, Metagross

Marshal: None

Iris: Lapras

HeartGold/SoulSilver(After 16 Badges):

Will: Jynx, Slowbro, Gardevoir

Koga: Toxicroak, Swalot, Venomoth

Bruno: Hitmontop, Hitmonchan, Hariyama, Lucario

Karen: None

Lance: Gyarados, Garchomp, Altaria

Platinum/Diamond/Pearl:

Aaron: None

Bertha: None

Flint: None

Lucian: Mr. Mime, Bronzong, Alakazam

Cynthia: Milotic, Lucario, Garchomp

So to answer your question, I would say that Shedinja is useful with beating the E4 in some games. It is great at taking out threats such as Cynthia's Garchomp, Lance's Gyarados, and Iris's Lapras. But overall, I would say it is most useful in Pokemon HGSS because of how much it walls.

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