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Zap Canon for Ampharos and Dynamic Punch for Typhlosion to be exact. In my opinion, the best moves for these Pkms.

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Typhlosion cannot learn DynamicPunch.
Ampharos cannot learn Zap Cannon.

Sorry :\
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Ok, edit: I just found out that Typhosion can learn DynamicPunch by tutor in Gen II.
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Ampharos can learn Zap Cannon by TM in Gen II.
Source
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In answer to your question, they both can't learn those moves by breeding.

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Yes, as of gen 2. But I'm wondering if these two pokemon can learn indirectly via breeding. A pokemon like Magnaton or Poliwrath, which can learn either move and is bread to these pokemon
true, true
They can't.
Not through breeding? I want to be sure if that's what you mean.
Yes, not through breeding. Ampharos cannot learn Zap cannon by breeding. Neither can Typhlosion.