PokéBase - Pokémon Q&A
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It is dark in there.

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Bulbapedia's article on caves doesn't list Hidden Grottoes, meaning they only qualify for the Dusk Ball boost at night.

Also note Pinwheel Forest doesn't receive the cave bonus for Dusk Balls. I'm not sure where the other answer got that information from.

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I searched around and I can't find a direct answer but the Dusk Ball's catch rate is;
>The Dusk Ball is a PokéBall that is more effective within Dark enviornments. Within Caves or at night-time, the Capture Rate is a massive 3.5. However, at any other times, the Capture Rate is 1

Since Dusk Ball works in Pinwheel forest against Virizion, it would probably work in Hidden Grottos. Could be wrong so woo xD

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Another great answer. Do you ever stop? Lol
Imma gonna see.