PokéBase - Pokémon Q&A
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In case you're reading this in the future, some of the exceptions can be found here: https://pokemondb.net/pokebase/250115/what-pokemon-that-give-their-highest-stat-stats-tied-highest

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For the most part all the pokemon follow this pattern. typhlosion's best stat is special attack and he yields 3 Sp atk EVs for instance. Some pokemon yield EVs in more than one stat too. There are a few weird ones though, so going by their best stat isn't 100% reliable. You can get a complete yield list right here. http://pokemondb.net/ev/all

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