PokéBase - Pokémon Q&A
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I know my Sylveon dodges moves and gets crits more often. It also gains boosted EXP but I'm not sure that's from Amie or not. It's not a traded Pokemon so its possible that its one of the boost from Pokemon-Amie but I'm not sure.

If your Pokémon are higher level than your badge level, it will obey you.
if its not traded it would do that anyways
No, from my experience, you can't overtrain.
only pokemon traded will stop obeying you. If you are the OT then they will never disobey you.

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Best answer

Yes the dodging, crits, and EXP boosts are from amie. Those are really the only befits besides the happiness boosts.
source: experience

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If affection is maxed out, your Pokemon will occasionally:

  • dodge attacks
  • land critical hits
  • recover from paralysis (and perhaps other afflictions, not sure)
  • gain more exp.
Sleep too....methinks also confusion.
Also burn, pretty sure all of them, if not most.